Synonymer & Oplysninger om | engelsk ord BIDENTATE

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Eksempler på brug af BIDENTATE i en sætning

• In contrast to other drugs of the platinum-based antineoplastic class of drugs cisplatin and carboplatin, oxaliplatin features the bidentate ligand trans-1,2-diaminocyclohexane in place of the two monodentate ammine ligands.
• A low reaction temperature favors para substitution and with high temperatures the ortho product prevails, this can be rationalised as exhibiting classic thermodynamic versus kinetic reaction control as the ortho product can form a more stable bidentate complex with the aluminium.
• Each lobe contains aspartic acid, histidine, 2 tyrosine residues and a bicarbonate ion that acts as a bidentate ligand to allow iron or other metals to bind to transferrin in a distorted octahedral geometry.
• The invariant Glu or Asp at position 12 provides two oxygens for liganding calcium (bidentate ligand).
• The bidentate yellow-eared bat (Vampyriscus bidens) is a species of bat in the family Phyllostomidae, native to South America.
• Picolinic acid is a bidentate chelating agent of elements such as chromium, zinc, manganese, copper, iron, and molybdenum in the human body.
• The Bailar twist is a mechanism proposed for the racemization of octahedral complexes containing three bidentate chelate rings.
• The Ray–Dutt twist is a mechanism proposed for the racemization of octahedral complexes containing three bidentate chelate rings.
• The bidentate yellow-shouldered bat (Sturnira bidens) is a species of bat in the family Phyllostomidae.
• These active sites resemble the motif seen in DMSO reductase, with two molybdopterin cofactors bound to Mo/W in a bidentate fashion.
• The head, round and small, has two robustly toothed antennae, the pronotum is furnished with longitudinal crests, and the elytra, covered by strong puncture, are bidentate at the apex.
• Diphosphines, sometimes called bisphosphanes, are organophosphorus compounds most commonly used as bidentate phosphine ligands in inorganic and organometallic chemistry.
• Once a catecholate substrate binds to the metal center in a bidentate fashion through the deprotonated hydroxyl groups, the ferric iron “activates” the substrate by means of abstracting an electron to produce a radical on the substrate.
• The diphosphine serves as a bidentate ligand forming six-membered CPM chelate ring with a natural bite angle of 91°.
• In the second reaction the bidentate ligand is replaced by two monodentate methylamine ligands of approximately the same donor power, meaning that the enthalpy of formation of Cu–N bonds is approximately the same in the two reactions.
• IDA forms stronger complexes than the bidentate ligand glycine and weaker complexes than the tetradentate ligand nitrilotriacetic acid.
• When the carboxyl group is deprotonated the glycinate ion can function as a bidentate ligand, binding the metal centre through the nitrogen and one of two carboxylate oxygen atoms, to form chelate complexes of metal ions.
• Two individual sublibraries can be assembled combinatorially and used for the de novo identification of bidentate binding molecules.
• While monodentate phosphine ligands such as triphenylphosphine and tricyclohexylphosphine are most common, bidentate phosphine ligands can also be useful in organoruthenium compounds.
• The glumes are leathery at the base; the lower, bidentate glume has two membranous wings in the apical half; the upper glume has a winged keel towards the apex and a 6 mm awn.
• The amidine group on NAPAP forms a bidentate salt bridge with Asp deep in the S1 pocket, the piperidine group takes the role of proline residue and binds in the S2 pocket, and the naphthyl rings of the molecule forms a hydrophobic interaction with Trp in the S4 pocket.
• The complex adopts an octahedral molecular geometry, containing two bidentate picolinate ligands (conjugate base of picolinic acid) and two aquo ligands.
• The neurochaetae are more slender and more numerous, have faint rows of spines distally, and feature minutely bidentate or simple (unidentate) tips.
• One nitrate is bonded with two oxygens to the aluminium (bidentate), and the other five oxygen atoms only link via one oxygen (monodentate).
• Also other thiols such as tiopronin, phenylethylthiolate, thiolate α-cyclodextrin and 3-mercaptopropionic acid and bidentate dihydrolipoic acid are other thiolated compounds currently being used in the synthesis of metal nanoclusters.

Sideforberedelse tog: 277,78 ms.